For their own preference, or bc their partner likes it. Occasionally, and usually at the request of her partner. In my experience, it's not the vast majority of women who typically rock their high heels during sexual activity.
Certainly, the wearing of high heels can sometimes precipitate sexual activity, but once the act is about to happen, or is happening, high heels are usually the first item of clothing to be cast off. Dependent upon any number of various fantasies, the wearing of high heels, stockings, leather or latex clothing or accessories, may be deemed integral to the scenario.
This is basically a fetish thing. If she or her partner like it, sure.
High heels are under fire as sexual harassment and assault allegations skyrocket
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